Cyclohexyl chloride

  1. Cyclohexyl chloride
  2. Cyclohexyl halides
  3. Cyclohexyl chloride, 98%, Thermo Scientific Chemicals, Quantity: 100 g
  4. Explain whyi the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?ii alkyl halides, though polar, are immiscible with water?iii Grignard reagents should be prepared under anhydrous conditions?
  5. Why is the dipole moment of the C
  6. 12.3: Conformations of Cycloalkanes


Download: Cyclohexyl chloride
Size: 80.70 MB

Cyclohexyl chloride

Listed are 10 international and reliable suppliers for Cyclohexyl chloride. They are coming from 5 countries around the world. These vendors belong to 2 different business types like 'Producer' and 'Analytical Institution' Please contact all the below listed distributors/manufacturers for Cyclohexyl chloride and ask for prices, package standards and transport possibilities. Our registered distributors will help you to get all necessary information and product specifications. Shandong Ench Chemical Co.Ltd is a professional manufacturers and supplier in the world ,the main product include chemical pharmaceuticals and intermediates, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc.It is a privet-owned enterprise and located in Zhangqiu industrial park, We believe that quality is the life of our company. Shandong Ench Chemical Co.,Ltd is supplier for Cyclohexyl chloride. We are seller of Austin Chemical Company, Inc. is starting its 4th decade of business and we find ourselves continuing to evolve into new areas and services in response to our customers needs and requests.We are expanding our global relationships with those suppliers that offer new and reliable services while continuing to grow the valued relationships with some of our historical suppliers. For over 17 years, Richman Chemical, Inc. (RCI) has been providing project management, custom manufacturing and sourcing services to the chemical and life sciences industries. RCI has an extens...

Cyclohexyl halides

• 180°C (5) • 166.0°C to 167.0°C (4) • 142°C (3) • 165°C (3) • 166°C to 167°C (3) • 75°C to 76°C (3) • 101°C to 102°C (2) • 103.0°C to 105.0°C (2) • 112°C (2) • 141°C to 143°C (2) • 143°C (2) • 145°C (100.0mmHg) (2) • 69°C (2) • 76°C (2) • 80.0°C to 81.0°C (20.0mmHg) (2) • 94°C to 96°C (50mmHg) (2) • 102°C (1) • 103°C to 105°C (1) • 104°C (1) • 125°C to 128°C (1) • 60°C (1) • 78°C (1) • 84°C to 86°C (8mmHg) (1)

Cyclohexyl chloride, 98%, Thermo Scientific Chemicals, Quantity: 100 g

CAS 542-18-7 Molecular Formula C 6H 11Cl Molecular Weight (g/mol) 118.61 MDL Number MFCD00003822 InChI Key UNFUYWDGSFDHCW-UHFFFAOYSA-N Synonym cyclohexyl chloride, cyclohexane, chloro, monochlorocyclohexane, chlorcyclohexan, chlorzyklohexan, unii-pnv8c821fh, pnv8c821fh, chlor-cyclohexane, cyclohexylchloride, chloro-cyclohexane PubChem CID ChEBI IUPAC Name chlorocyclohexane SMILES C1CCC(CC1)Cl This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals. Melting Point -44°C Density 1.0000g/mL Boiling Point 142°C Flash Point 28°C Infrared Spectrum Authentic Assay Percent Range 97.5% min. (GC) Packaging Glass bottle Refractive Index 1.4610 to 1.463 Linear Formula C 6H 1 1Cl Quantity 100 g Beilstein 05, 21 Specific Gravity 1 Merck Index 15, 2725 Solubility Information Solubility in water: 0.02g/L (20°C). Other solubilities: soluble in alcohol and diethyl ether Viscosity 1.73 mPa.s (20°C) Formula Weight 118.61 Percent Purity 98% Physical Form Liquid Chemical Name or Material Cyclohexyl chloride, 98% GHS H Statement: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Flammable liquid and vapor. GHS P Statement: Avoid breathing dust/fume/gas/mist/vapors/spray. IF ON SKIN: Wash with ...

Explain whyi the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?ii alkyl halides, though polar, are immiscible with water?iii Grignard reagents should be prepared under anhydrous conditions?

(i) In chlorobenzene, the Cl-atom is linked to a sp 2 hybridized carbon atom. In cyclohexyl chloride, the Cl-atom is linked to a sp 3 hybridized carbon atom. Now, sp 2 hybridized carbon has more s-character than sp 3 hybridized carbon atom. Therefore, the former is more electronegative than the latter. Therefore, the density of electrons of C−Cl bond near the Cl-atom is less in chlorobenzene than in cydohexyl chloride. Moreover, the −R effect of the benzene ring of chlorobenzene decreases the electron density of the C−Cl bond near the Cl-atom. As a result, the polarity of the C−Cl bond in chlorobenzene decreases. Hence, the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride. (ii) To be miscible with water, the solute-water force of attraction must be stronger than the solute-solute and water-water forces of attraction. Alkyl halides are polar molecules and so held together by dipole-dipole interactions. Similarly, strong H-bonds exist between the water molecules. The new force of attraction between the alkyl halides and water molecules is weaker than the alkyl halide-alkyl halide and water-water forces of attraction. Hence, alkyl halides (though polar) are immiscible with water. (iii) Grignard reagents are very reactive. In the presence of moisture, they react to give alkanes. Therefore, Grignard reagents should be prepared under anhydrous conditions.

Why is the dipole moment of the C

There are a couple of factors that contribute to the lower dipole moment for the #"C-Cl"# bond in chlorobenzene. Take a look at the two molecules, chlorobenzene and cyclohexyl chloride Notice that the chlorine atoms are attached to carbon atoms that have a different #"2p"^2# hybridized, while in cyclohexyl chloride, that carbon is #"sp"^3# hybridized. That has an impact on dipole moment because the greater the s character of the hybrid orbital, the more #"sp"^2# hybridized carbon will have less stendency to release electrons to the chlorine atom, which in turn will make the dipole moment weaker when compared with the #"sp"^3# hybridized carbon's bond with chlorine. Another important factor is the fact that chlorobenzene is delocalized on the benzene ring . As a result, the #"C-Cl"# single bond will acquire some double bond character. Double bonds are shorter than single bonds, which has a direct impact on dipole moment because dipole moment depends on charge and distance. By comparison, the #"C-Cl"# is a pure single bond, which means, of course, that it will be longer. These two factors are what determine the dipole moment for the #"C-Cl"# bond in chlorobenzene to be lower, or weaker, than the dipole moment of the same bond in cyclohexyl chloride.

12.3: Conformations of Cycloalkanes

\( \newcommand\) • • • • • • • • • The equilibria (relative stabilities) and equilibration (rate of interconversion) of the rotational conformations of ethane and butane were discussed in Section 5-2. If you review this material, it will be clear that forming a ring from a hydrocarbon chain will greatly reduce the number of possible staggered and eclipsed conformations. We will begin our discussion with cyclohexane because of its special importance, proceed to smaller rings, then give a brief exposition of the conformations of the larger rings. Cyclohexane Conformations If the carbons of a cyclohexane ring were placed at the corners of a regular planar hexagon, all the \(\ce\), the normal equilibrium favoring the chair form is established in a short time. Dreiding Models The spatial arrangement (stereochemistry) of cyclohexane and other organic compounds are studied conveniently with the aid of Dreiding models, which are made with standard bond angles and scaled bond distances. The bonds have stainless-steel rods that make a snap-fit into stainless-steel sleeves. Rotation is smooth about the bonds and there is sufficient flexibility to accommodate some angle strain. Dreding models of the conformations of cyclohexane are shown in Figure 12-7. Notice that these models correspond closely to the sawhorse representations in Figures 12-4, 12-5, and 12-6. Figure 12-7: Dreiding models of the cyclohexane conformations. Conformational Equilibria and Equilibration for Cyclohexane Der...