Naco3

  1. Sodium carbonate CAS 497
  2. 4.8: Acid
  3. inorganic chemistry


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Sodium carbonate CAS 497

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4.8: Acid

\( \newcommand\) • • • • • • How They Work A modification of the extractions previously discussed in this chapter is to perform a chemical reaction in the separatory funnel in order to change the polarity and therefore partitioning of a compound in the aqueous and organic layers. A common method is to perform an acid-base reaction, which can convert some compounds from neutral to ionic forms (or vice versa). For example, imagine that a mixture of benzoic acid and cyclohexane is dissolved in an organic solvent like ethyl acetate in a separatory funnel. To separate the components, a water wash may be attempted to remove benzoic acid, but benzoic acid is not particularly water-soluble due to its nonpolar aromatic ring, and only small amounts would be extracted into the aqueous layer (Figure 4.54a). Figure 4.54: Washing a mixture of benzoic acid and cyclohexane with: a) water, b) aqueous \(\ce \left( aq \right)\) if desired to convert the benzoic acid back to its neutral form. Sodium Bicarbonate Washes An acid-base extraction can be used to extract carboxylic acids from the organic layer into the aqueous layer. As was discussed in the previous section, \(\ce\) could cause hydrolysis of the ester product. Extracting Bases Basic compounds such as amines can be extracted from organic solutions by shaking them with acidic solutions to convert them into more water-soluble salts. In this way, they can be extracted from an organic layer into an aqueous layer. \[\begin\] Extracting Ca...

inorganic chemistry

The 2 steps to the reaction between $\ce$ upon formation) Why wouldn't this be the case? Why must step 2 only occur after step 1 is completed? You are right. When adding a small amount of $\ce$ There are two ways to react sodium carbonate (A) with hydrochloric acid (B): • You can add A to B, or • You can add B to A. If the ratios differ from 1:1, you can get different reaction products by adding them differently. For instance, if you dump (A to B) a solution of 0.1 mole of Na $_2$CO $_3$ into a solution of 0.1 mole of HCl at a moderate rate, with stirring, the products will be 0.05 moles of CO $_2$ fizzing off instantly, plus 0.1 moles of NaCl, plus 0.05 moles of unreacted Na $_2$CO $_3$. You won't find any NaHCO $_3$ because your reaction Step 2 occurs rapidly enough to go to completion before all the Na $_2$CO $_3$ has been added. You have Steps 1 and 2 occurring for half of the Na $_2$CO $_3$, leaving half of the Na $_2$CO $_3$ unreacted. This scheme conforms to your supposition, but is not elegant chemical technique. On the other hand, if you add, slowly, by using a tube to add (B to A) 0.1 mole of Na $_2$CO $_3$ at the bottom of a solution of 0.1 mole of HCl, something like the picture, you should be able to get a solution of 0.1 mole of NaHCO $_3$ plus 0.1 mole of NaCl. All the CO $_2$ will have been trapped and no bubbling out will have occurred. This is not as easy as it looks, and requires a lot of patience, but is a clear demonstration of your reaction Step 1.